Date

8-1-2018

Document Type

Dissertation

Degree

Doctor of Philosophy

Department

Materials Science and Engineering

First Adviser

Kiely, Chistopher J.

Abstract

Catalysis by nanoscopic metal structures, ranging from nanoparticles to sub-nm clusters and even individual atoms, is amongst the most intensely studied topics in nanoscience. The catalytic performance of supported metal nanoparticles is governed by their crysallographic structure, shape, size, composition and interaction with the support. Aberration-corrected scanning transmission electron microscopy (AC-STEM), with its ultra-high spatial resolution for imaging and compositional analysis, is an ideal tool for characterizing such features in metallic nanocatalysts. In this thesis, five case studies are presented where AC-STEM has been invaluable in elucidating synthesis route - structure - performance relationships in some technologically important catalyst systems.

Share

COinS